Kinetics and Mechanism of the Reaction of Catalytic Dehydroaromatization of Methane

Normurot I. Fayzullaev; Bakhriddin Sh. Shukurov; Abdulatif O’. Normuminov

doi:doi:10.11648/j.ogce.20170506.11

| Peer-Reviewed

Kinetics and Mechanism of the Reaction of Catalytic Dehydroaromatization of Methane

Normurot I. Fayzullaev, Bakhriddin Sh. Shukurov, Abdulatif O’. Normuminov

Published in International Journal of Oil, Gas and Coal Engineering (Volume 5, Issue 6)

Received: 24 February 2017 Accepted: 27 May 2017 Published: 31 October 2017

Views: Downloads:

Download PDF

Share This Article

Twitter
Linked In
Facebook

Abstract

In the work the influence of various parameters on methane conversion and reaction yield of the reaction of methane dehydroaromatization was studied. Based on obtained results the mechanisms of activation of the methane molecule and proceeding of the process were offered. Kinetic equations of formation reactions of coke, benzene, toluene, xylene were improved and expressed in terms of the Langmuir-Hinshelwood equation.

Published in	International Journal of Oil, Gas and Coal Engineering (Volume 5, Issue 6)
DOI	10.11648/j.ogce.20170506.11
Page(s)	124-129
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Methane, Dehydroaromatization, Catalyst, Activation Mechanism, Kinetic Equation

References

[1]	B. Tuktin, L. B. Shapovalova, R. I. Egizbaeva, A.A.Shapovalov. Nonoxidative conversion of methane to aromatic hydrocarbons on Mo/Al₂O₃ and Mo-Co/ Al₂O₃ catalysts promoted by ZSM zeolite // Izvestiya NAS RK. A series of chemistry and technology. - 2013. - No. 6. - P. 46-51.
[2]	B. Tuktin, L. B. Shapovalova, R. I. Egizbaeva. Catalytic and physico-chemical properties of monometallic molybdenum catalysts of non-oxidative conversion of methane //European Applied Sciences. - 2014. - №10. - R.116-120.
[3]	J. Gao, Y. Zheng, J. Joannis, Y. Tang, I. E. Wachs, S. G. Podkolozin. Structure of nanoparticles of molybdenum carbide Mo₂C_x and Mo₄C_x and anchorage points on ZSM-5 zeolite // J. Phys. Chemical reagent -2014. -No 118. -P. 4670-4679.
[4]	B. T. Tuktin, L. B. Shapovalova. Mechanism of non-oxidative conversion of methane on molybdenum-containing apparatus (review) // Izvestiya NAS RK. A series of chemistry and technology. -2015. -No 6.-C.40-50.
[5]	Ya. E. Barbashin, A. V. Vosmerikov, L. L. Korobitsyna, A. A. Stepanov. Influence of the conditions of preliminary heat treatment on the properties of Mo/ZSM-5 - catalysis of non-oxidative conversion of methane. // Journal of Physical Chemistry. -2016. -V. 90. - No. 12. - P. 1797-1803.
[6]	L. L. Korobitsyna, V. V. Kozlov, A. V. Vosmerikov. Non-oxidative conversion of methane on Mo-containing zeolites //Bulletin of the Tomsk Polytechnic University. Chemistry and chemical technologies. -2014. -V. 325.-No. 3. P. 71-77.
[7]	L.M. Velichkina et al. Influence of the structural type of zeolite on its isomerizing activity in the process of n-alkane conversion // Oil refining and petrochemistry. Scientific and technical achievements and best practices. - 2016. - No. 8. - P. 29-36.
[8]	N. A. Mamanov, E. V. Fadeeva, D. A. Grigorev, M. N. Mikhaylov, L. M. Kustov, S. A. Alkhimov. “Metal bentonite catalysts for methane dehydroaromatization,” Uspekhi khimii. 2013, Vol. 82, N 6, pp. 567-585.
[9]	A. V. Vosmerikov, G. V. Echevskiy, L. L. Korobitsyna, Ya. E. Barbashin. “Dezactivation of Mo-containing bentonites in the process of non-oxidative conversion of methane,” Kinetika i kataliz, 2005, V 46, №5, pp. 769-772.
[10]	Z. R. Ismagilov, B. V. Matus, M. A. Kerjentsev, L. T. Tsikoza, I. Z. Ismagilov. “Methane conversion in valuable products in the presence of nanostructurized Mo/HZSM-5-catalysts,” Nephtekhimiya, 2011, V 51, №3, pp. 186-198.
[11]	B. Tuktin, L. B. Shapovalova, R. I. Egizbaeva, L. V. Komashko. “Non-oxidative conversion of methane in aromatic hydrocarbons on monometallic molybdenum containing catalysts,” Izvestiya NAN RK, Seriya khimiya i tekhnologiya, 2013, №6, pp. 40-45.
[12]	S. Ma, X. Guo, L. Zhao, S. Scott, X. Bao. “Recent progress in methane dehydroaromatization: from laboratory curiosities to promising technology,” J. of Energy Chemistry, 2013, V. 22. pp. 1-20.
[13]	N. I. Fayzullayev, S. M. Turobjonov. “Catalytic Aromatization of Methane,” International Journal of Chemical and Physical Science, 2015, V. 4, №-4, pp. 27-34.

Cite This Article

Plain Text BibTeX RIS

APA Style

Normurot I. Fayzullaev, Bakhriddin Sh. Shukurov, Abdulatif O’. Normuminov. (2017). Kinetics and Mechanism of the Reaction of Catalytic Dehydroaromatization of Methane. International Journal of Oil, Gas and Coal Engineering, 5(6), 124-129. https://doi.org/10.11648/j.ogce.20170506.11

Copy | Download

ACS Style

Normurot I. Fayzullaev; Bakhriddin Sh. Shukurov; Abdulatif O’. Normuminov. Kinetics and Mechanism of the Reaction of Catalytic Dehydroaromatization of Methane. Int. J. Oil Gas Coal Eng. 2017, 5(6), 124-129. doi: 10.11648/j.ogce.20170506.11

Copy | Download

AMA Style

Normurot I. Fayzullaev, Bakhriddin Sh. Shukurov, Abdulatif O’. Normuminov. Kinetics and Mechanism of the Reaction of Catalytic Dehydroaromatization of Methane. Int J Oil Gas Coal Eng. 2017;5(6):124-129. doi: 10.11648/j.ogce.20170506.11

Copy | Download

@article{10.11648/j.ogce.20170506.11,
  author = {Normurot I. Fayzullaev and Bakhriddin Sh. Shukurov and Abdulatif O’. Normuminov},
  title = {Kinetics and Mechanism of the Reaction of Catalytic Dehydroaromatization of Methane},
  journal = {International Journal of Oil, Gas and Coal Engineering},
  volume = {5},
  number = {6},
  pages = {124-129},
  doi = {10.11648/j.ogce.20170506.11},
  url = {https://doi.org/10.11648/j.ogce.20170506.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ogce.20170506.11},
  abstract = {In the work the influence of various parameters on methane conversion and reaction yield of the reaction of methane dehydroaromatization was studied. Based on obtained results the mechanisms of activation of the methane molecule and proceeding of the process were offered. Kinetic equations of formation reactions of coke, benzene, toluene, xylene were improved and expressed in terms of the Langmuir-Hinshelwood equation.},
 year = {2017}
}

Copy | Download

TY  - JOUR
T1  - Kinetics and Mechanism of the Reaction of Catalytic Dehydroaromatization of Methane
AU  - Normurot I. Fayzullaev
AU  - Bakhriddin Sh. Shukurov
AU  - Abdulatif O’. Normuminov
Y1  - 2017/10/31
PY  - 2017
N1  - https://doi.org/10.11648/j.ogce.20170506.11
DO  - 10.11648/j.ogce.20170506.11
T2  - International Journal of Oil, Gas and Coal Engineering
JF  - International Journal of Oil, Gas and Coal Engineering
JO  - International Journal of Oil, Gas and Coal Engineering
SP  - 124
EP  - 129
PB  - Science Publishing Group
SN  - 2376-7677
UR  - https://doi.org/10.11648/j.ogce.20170506.11
AB  - In the work the influence of various parameters on methane conversion and reaction yield of the reaction of methane dehydroaromatization was studied. Based on obtained results the mechanisms of activation of the methane molecule and proceeding of the process were offered. Kinetic equations of formation reactions of coke, benzene, toluene, xylene were improved and expressed in terms of the Langmuir-Hinshelwood equation.
VL  - 5
IS  - 6
ER  -

Copy | Download

Author Information

Normurot I. Fayzullaev

Department of Biology and Chemistry, Samarkand State University, Samarkand, Uzbekistan
Bakhriddin Sh. Shukurov

Department of Natural Sciences, Navoi State Pedagogical Institute, Navoi, Uzbekistan
Abdulatif O’. Normuminov

Department of Biology and Chemistry, Samarkand State University, Samarkand, Uzbekistan

Download PDF

Sections

Plain Text BibTeX RIS

APA Style

Normurot I. Fayzullaev, Bakhriddin Sh. Shukurov, Abdulatif O’. Normuminov. (2017). Kinetics and Mechanism of the Reaction of Catalytic Dehydroaromatization of Methane. International Journal of Oil, Gas and Coal Engineering, 5(6), 124-129. https://doi.org/10.11648/j.ogce.20170506.11

Copy | Download

ACS Style

Normurot I. Fayzullaev; Bakhriddin Sh. Shukurov; Abdulatif O’. Normuminov. Kinetics and Mechanism of the Reaction of Catalytic Dehydroaromatization of Methane. Int. J. Oil Gas Coal Eng. 2017, 5(6), 124-129. doi: 10.11648/j.ogce.20170506.11

Copy | Download

AMA Style

Normurot I. Fayzullaev, Bakhriddin Sh. Shukurov, Abdulatif O’. Normuminov. Kinetics and Mechanism of the Reaction of Catalytic Dehydroaromatization of Methane. Int J Oil Gas Coal Eng. 2017;5(6):124-129. doi: 10.11648/j.ogce.20170506.11

Copy | Download

@article{10.11648/j.ogce.20170506.11,
  author = {Normurot I. Fayzullaev and Bakhriddin Sh. Shukurov and Abdulatif O’. Normuminov},
  title = {Kinetics and Mechanism of the Reaction of Catalytic Dehydroaromatization of Methane},
  journal = {International Journal of Oil, Gas and Coal Engineering},
  volume = {5},
  number = {6},
  pages = {124-129},
  doi = {10.11648/j.ogce.20170506.11},
  url = {https://doi.org/10.11648/j.ogce.20170506.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ogce.20170506.11},
  abstract = {In the work the influence of various parameters on methane conversion and reaction yield of the reaction of methane dehydroaromatization was studied. Based on obtained results the mechanisms of activation of the methane molecule and proceeding of the process were offered. Kinetic equations of formation reactions of coke, benzene, toluene, xylene were improved and expressed in terms of the Langmuir-Hinshelwood equation.},
 year = {2017}
}

Copy | Download

TY  - JOUR
T1  - Kinetics and Mechanism of the Reaction of Catalytic Dehydroaromatization of Methane
AU  - Normurot I. Fayzullaev
AU  - Bakhriddin Sh. Shukurov
AU  - Abdulatif O’. Normuminov
Y1  - 2017/10/31
PY  - 2017
N1  - https://doi.org/10.11648/j.ogce.20170506.11
DO  - 10.11648/j.ogce.20170506.11
T2  - International Journal of Oil, Gas and Coal Engineering
JF  - International Journal of Oil, Gas and Coal Engineering
JO  - International Journal of Oil, Gas and Coal Engineering
SP  - 124
EP  - 129
PB  - Science Publishing Group
SN  - 2376-7677
UR  - https://doi.org/10.11648/j.ogce.20170506.11
AB  - In the work the influence of various parameters on methane conversion and reaction yield of the reaction of methane dehydroaromatization was studied. Based on obtained results the mechanisms of activation of the methane molecule and proceeding of the process were offered. Kinetic equations of formation reactions of coke, benzene, toluene, xylene were improved and expressed in terms of the Langmuir-Hinshelwood equation.
VL  - 5
IS  - 6
ER  -

Copy | Download