With nano-alumina modified by the fat acid as an inorganic template for making pores, a new kind of porous resin particle with the large surface was synthesized by emulsion polymerization. Moreover, the sulfonated polystyrene resin was fluorinated to increase its acid strength up to Ho 8.6 and the acid amount of 4.1mmol/g. The ratio of butane to water was increased by packing the catalytic resin with the fixed beds of four stages. Under reaction temperature of 168-174°C, butane to water ratio of 2 mol/mol and WHSV1.0 h-1, hydration reaction conversion was over 15 wt%, with the butyl alcohol selectivity of 99 wt% and a good thermal stability.
| Published in | Science Discovery (Volume 4, Issue 2) |
| DOI | 10.11648/j.sd.20160402.23 |
| Page(s) | 137-141 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2016. Published by Science Publishing Group |
Butene Hydration, Pores, Acid Resin, Catalyst, Reaction Performance
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APA Style
Cai Jian-guo, Shi Hong-yan, Zhu Zhi-rong, Shi Xiao-li. (2016). Porous Resin Catalyst with Strong Acidity for Hydration Reaction of Butane and Its Catalytic Performance. Science Discovery, 4(2), 137-141. https://doi.org/10.11648/j.sd.20160402.23
ACS Style
Cai Jian-guo; Shi Hong-yan; Zhu Zhi-rong; Shi Xiao-li. Porous Resin Catalyst with Strong Acidity for Hydration Reaction of Butane and Its Catalytic Performance. Sci. Discov. 2016, 4(2), 137-141. doi: 10.11648/j.sd.20160402.23
AMA Style
Cai Jian-guo, Shi Hong-yan, Zhu Zhi-rong, Shi Xiao-li. Porous Resin Catalyst with Strong Acidity for Hydration Reaction of Butane and Its Catalytic Performance. Sci Discov. 2016;4(2):137-141. doi: 10.11648/j.sd.20160402.23
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Download@article{10.11648/j.sd.20160402.23,
author = {Cai Jian-guo and Shi Hong-yan and Zhu Zhi-rong and Shi Xiao-li},
title = {Porous Resin Catalyst with Strong Acidity for Hydration Reaction of Butane and Its Catalytic Performance},
journal = {Science Discovery},
volume = {4},
number = {2},
pages = {137-141},
doi = {10.11648/j.sd.20160402.23},
url = {https://doi.org/10.11648/j.sd.20160402.23},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sd.20160402.23},
abstract = {With nano-alumina modified by the fat acid as an inorganic template for making pores, a new kind of porous resin particle with the large surface was synthesized by emulsion polymerization. Moreover, the sulfonated polystyrene resin was fluorinated to increase its acid strength up to Ho 8.6 and the acid amount of 4.1mmol/g. The ratio of butane to water was increased by packing the catalytic resin with the fixed beds of four stages. Under reaction temperature of 168-174°C, butane to water ratio of 2 mol/mol and WHSV1.0 h-1, hydration reaction conversion was over 15 wt%, with the butyl alcohol selectivity of 99 wt% and a good thermal stability.},
year = {2016}
}
TY - JOUR T1 - Porous Resin Catalyst with Strong Acidity for Hydration Reaction of Butane and Its Catalytic Performance AU - Cai Jian-guo AU - Shi Hong-yan AU - Zhu Zhi-rong AU - Shi Xiao-li Y1 - 2016/05/19 PY - 2016 N1 - https://doi.org/10.11648/j.sd.20160402.23 DO - 10.11648/j.sd.20160402.23 T2 - Science Discovery JF - Science Discovery JO - Science Discovery SP - 137 EP - 141 PB - Science Publishing Group SN - 2331-0650 UR - https://doi.org/10.11648/j.sd.20160402.23 AB - With nano-alumina modified by the fat acid as an inorganic template for making pores, a new kind of porous resin particle with the large surface was synthesized by emulsion polymerization. Moreover, the sulfonated polystyrene resin was fluorinated to increase its acid strength up to Ho 8.6 and the acid amount of 4.1mmol/g. The ratio of butane to water was increased by packing the catalytic resin with the fixed beds of four stages. Under reaction temperature of 168-174°C, butane to water ratio of 2 mol/mol and WHSV1.0 h-1, hydration reaction conversion was over 15 wt%, with the butyl alcohol selectivity of 99 wt% and a good thermal stability. VL - 4 IS - 2 ER -
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